I always wanted a
pair of real ruby slippers; I think most young girls having watched “The Wizard
of Oz” do. However, with my recent
knowledge on the ruby market; I’m not so sure.
Apparently there are some fundamental misunderstandings when it comes to
flux in Rubies. You see we have been led
to believe that flux was an unavoidable “residue” left over from the heating
process and that borax was used to protect the stone from the heat.
Dr. John Emmett,
President of Crystal Chemistry in Brush Prairie, Washington says that the flux which is
present in some processed rubies is NOT a “residue”; but rather an infiltration
that is fundamental to the processing.
In fact it is as fundamental as impregnating emeralds with oils or
plastics to REDUCE THE VISIBILITY OF FRACTURES.
In laymen’s terms;
borax is to a ruby what oil is to an emerald: make up. It is solely for the purpose of hiding
fractures and imperfections. You see
Borax (AKA: Sodium Tetraborite Decahydrate) starts to decompose by losing water
at 80 degrees Celsius and the anhydrous material melts at 741 degrees Celsius. This means that its melting point is well
below the heat temperature for treating gems which is 1600-1759 degrees
Celsius. Therefore it could not by any
stretch of the imagination protect the stone from the heat.
In fact, you can
drop natural corundum out of a furnace and into a bucket of water with out
cracking it. Apparently every heat
treater knows this, it’s common knowledge among those whom are in the
business of heat treating gems.
To avoid getting too
far down the rabbit hole of chemistry here, I’m gonna break it down. Some Rubies contain deposits of Aluminum Hydroxide,
which when heated turns into Aluminum Oxide.
Aluminum Oxide is amorphous and scatters light poorly (not so shiny L) it also leaves fissures or cracks in the
stone. In comes molten Borax, which
wicks into the fissures dissolving the Aluminum Oxide. These two components combined create
Alumino-Borate compounds. These compounds
have high indicies of refraction and thereby do a fair job of matching the
corundum; just as oils do for emeralds.
This is all fine and
well when one knows they are buying a ruby with fissures that have been patched;
rather than a ruby with natural “residue” from the heat treatment. Gemologists now understand this misrepresentation,
but the industry has called these fissure repairs “residue” for so long and has
increased acceptance of the material, so the term remains.